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Scientists invent method to extract gold from liquid waste

The next gold rush might take place in our sewers.

  • Even though we think of it as exceedingly rare, gold can be found all around us.
  • The trouble is, most of the gold is hard to get at; its too diluted in our waste or ocean waters to effectively extract.
  • This new technique quickly, easily, and reliably extracts gold from most liquids.

Even though the thought of gold calls to mind incredible wealth hidden underground or horded away in Fort Knox, you can actually find the stuff all over the place. there's gold in nearly every kind of consumer electronic, gold in our sewage, gold in the cracks of New York City sidewalks, and even trace amounts in our brains. The trouble isn't that gold is rare, per se, it's just hard to get to.

In human history, we've mined about 190,000 tons of gold out of the ground. If you want to visualize that amount, it would fit in a box about 20 m on each side; not all that much in the grand scheme of things. We've been able to get at this because it was stored in a way that's relatively easy for us to access. It was buried in the Earth, so we just had to dig it up. In contrast, we've estimated that there's about 20 million tons of gold in the ocean—it's just distributed throughout the seas, making it difficult to refine and extract.

In the past, we didn't use gold for much of anything besides as a method to store value, so the fact that most gold on Earth was inaccessible was more of a feature than a bug. But now, we're increasingly finding practical applications for the precious metal. It can be used in medicine to treat arthritis or for dentistry; it's an excellent conductor, so it can be used in electronics and communication technology; and it reflects infrared radiation, so we use it on our spacecraft and spacesuits. Suddenly, getting at those 20 million tons of gold in the ocean and elsewhere on Earth has become more about technological and societal progress than about accumulating wealth.

New research from the Journal of the American Chemical Society has uncovered one of the most effective methods to date to extract gold from liquids. That includes electronic waste, sewage, ocean water, waste water—almost any liquid where we might find gold. Just to highlight how potentially useful this is, sewage from Switzerland alone is estimated to carry away 1.8 million dollars' worth of gold every year.

Making a sponge for gold

The object to the left shows the basic framework, a lattice of iron ion clusters connected by organic molecules. On this structure, a polymer that helps catch gold is coated, represented by the purple dots.

Sun et al. 2018

The method consists of a metal-organic framework—essentially, clusters metal ions connected by an organic "skeleton." In this case, the framework consists of iron ions connected by an organic compound called 1,3,5-benzenetricarboxylate. The researchers then coated this structure in a polymer with an even more difficult-to-pronounce name (for the curious, it's poly-para-phenylenediamine, or PpDA), which helps the framework catch stray molecules of gold.

Essentially, the framework and polymer work as a very granular sponge, only this sponge doesn't hold soap or water; instead, it holds gold.

Other researchers have built structures like this one before, but the new framework works exceptionally well. For every gram of this gold-seeking sponge submerged in a liquid, it can hold up to a gram of gold. What's more, it can catch 99% of the gold in a given solution in as little as two minutes.

Once the framework's sucked up the gold, it can easily be destroyed to retrieve the gold captured inside. The figure below shows how this works. After it's been suspended in a gold-containing solution, the framework is dissolved in hydrochloric acid. After some time, all that's left is 23.9 K gold, which is the highest purity of gold reclaimed from similar projects.

On the left, a sample of liquid is shown with the new material suspended inside. After the material is dissolved in acid, 23.9 K gold particles are leftover. On the right side, the gold particles are shown under a microscope.

Sun et al. 2018

The researchers tested the method out in a few different real-world cases. One of the most useful applications for a method like this is in reclaiming gold from electronic waste. It can take as much as a ton of gold ore to build just 40 smartphones, so getting the gold out of electronic waste would be extremely practical.

The researchers physically removed the metal from a CPU and treated it with some chemicals to form a solution. In the figure below, you can see that this produced a blue solution. So far, this technique is nothing new. The trouble is that a CPU also contains copper and nickel as well as gold, all of which is mixed up in this solution. So, the trick is how to get the really valuable metal out of the mixture. Using the new method, the researchers managed to get 95% of the gold out of the solution.

The top-left image shows a regular CPU. To its right, we can see the various elements that comprise the CPU (copper, nickel, and gold). In the bottom-left corner, we can see the CPU after its material has been physically removed. The image to its right shows the material dissolved into a blue solution and a graph showing how much of each material the new method recovered from the solution.

Sun et al. 2018

They found similar results with different liquids, too. The new framework captured 99% of gold from Swiss sewage (which, if you'll recall, allegedly washes away $1.8 million worth of gold every year). The researchers also tried extracting gold from seawater, and, once again, they were able to extract 99% of gold from their sample. These last two examples are especially promising; sewage and seawater contain a huge variety of different compounds that could interfere with any kind of filtering system.

We're still a long way off from, say, filtering the oceans for the precious metals they contain. But as we continue to use up the easily accessible resources buried in the Earth, exploring new techniques like this will be important if we want to continue to use smartphones, explore space, and collectively advance as a society.

Hulu's original movie "Palm Springs" is the comedy we needed this summer

Andy Samberg and Cristin Milioti get stuck in an infinite wedding time loop.

  • Two wedding guests discover they're trapped in an infinite time loop, waking up in Palm Springs over and over and over.
  • As the reality of their situation sets in, Nyles and Sarah decide to enjoy the repetitive awakenings.
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Two MIT students just solved Richard Feynman’s famed physics puzzle

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Our ‘little brain’ turns out to be pretty big

The multifaceted cerebellum is large — it's just tightly folded.

Image source: Sereno, et al
Mind & Brain
  • A powerful MRI combined with modeling software results in a totally new view of the human cerebellum.
  • The so-called 'little brain' is nearly 80% the size of the cerebral cortex when it's unfolded.
  • This part of the brain is associated with a lot of things, and a new virtual map is suitably chaotic and complex.

Just under our brain's cortex and close to our brain stem sits the cerebellum, also known as the "little brain." It's an organ many animals have, and we're still learning what it does in humans. It's long been thought to be involved in sensory input and motor control, but recent studies suggests it also plays a role in a lot of other things, including emotion, thought, and pain. After all, about half of the brain's neurons reside there. But it's so small. Except it's not, according to a new study from San Diego State University (SDSU) published in PNAS (Proceedings of the National Academy of Sciences).

A neural crêpe

A new imaging study led by psychology professor and cognitive neuroscientist Martin Sereno of the SDSU MRI Imaging Center reveals that the cerebellum is actually an intricately folded organ that has a surface area equal in size to 78 percent of the cerebral cortex. Sereno, a pioneer in MRI brain imaging, collaborated with other experts from the U.K., Canada, and the Netherlands.

So what does it look like? Unfolded, the cerebellum is reminiscent of a crêpe, according to Sereno, about four inches wide and three feet long.

The team didn't physically unfold a cerebellum in their research. Instead, they worked with brain scans from a 9.4 Tesla MRI machine, and virtually unfolded and mapped the organ. Custom software was developed for the project, based on the open-source FreeSurfer app developed by Sereno and others. Their model allowed the scientists to unpack the virtual cerebellum down to each individual fold, or "folia."

Study's cross-sections of a folded cerebellum

Image source: Sereno, et al.

A complicated map

Sereno tells SDSU NewsCenter that "Until now we only had crude models of what it looked like. We now have a complete map or surface representation of the cerebellum, much like cities, counties, and states."

That map is a bit surprising, too, in that regions associated with different functions are scattered across the organ in peculiar ways, unlike the cortex where it's all pretty orderly. "You get a little chunk of the lip, next to a chunk of the shoulder or face, like jumbled puzzle pieces," says Sereno. This may have to do with the fact that when the cerebellum is folded, its elements line up differently than they do when the organ is unfolded.

It seems the folded structure of the cerebellum is a configuration that facilitates access to information coming from places all over the body. Sereno says, "Now that we have the first high resolution base map of the human cerebellum, there are many possibilities for researchers to start filling in what is certain to be a complex quilt of inputs, from many different parts of the cerebral cortex in more detail than ever before."

This makes sense if the cerebellum is involved in highly complex, advanced cognitive functions, such as handling language or performing abstract reasoning as scientists suspect. "When you think of the cognition required to write a scientific paper or explain a concept," says Sereno, "you have to pull in information from many different sources. And that's just how the cerebellum is set up."

Bigger and bigger

The study also suggests that the large size of their virtual human cerebellum is likely to be related to the sheer number of tasks with which the organ is involved in the complex human brain. The macaque cerebellum that the team analyzed, for example, amounts to just 30 percent the size of the animal's cortex.

"The fact that [the cerebellum] has such a large surface area speaks to the evolution of distinctively human behaviors and cognition," says Sereno. "It has expanded so much that the folding patterns are very complex."

As the study says, "Rather than coordinating sensory signals to execute expert physical movements, parts of the cerebellum may have been extended in humans to help coordinate fictive 'conceptual movements,' such as rapidly mentally rearranging a movement plan — or, in the fullness of time, perhaps even a mathematical equation."

Sereno concludes, "The 'little brain' is quite the jack of all trades. Mapping the cerebellum will be an interesting new frontier for the next decade."

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Politics & Current Affairs
  • A recently published study suggests that some welfare programs more than pay for themselves.
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